There is no data on spectrum loss over time for aquarium use that I know of. This is more important than par levels. I do agree failure of the electronic parts that support the diodes are what's more in question.
The UV diodes400-420 do burn out/blacken the plastic and need replacing. I don't know about other colors.
The fact of the matter is most people kept upgrading and buying newer LED units that lacked success due to poor design, spectrum limitations, ect. so there really isn't any data on much of this over actual aquariums.
Most of this is more critical with Acropora in reference to color and growth...........for a standard reef it isn't as much of a concern.
In your case, they're just old not over used so they should be fine to use again.
If you're going to focus on a dominant Acropora system I would consider adding violet diodes and making sure you cover your tank from edge to edge with light. Another option is to add some T5 to the mix which would be easier.