I reread your post from the other day. Your alk is too high and could be to blame for stn. You could do bio pellets or vodka dosing to get no3 down and keep it there. I suggest biopellets as its easier to do.
There are a lot of factors that can keep no3 high. Do you use a filter bag and how often do you clean it? Do you have a small powerhead in your sump to keep detritus from settling? Do you use a turkey baster and blow out your rocks before a water change? Doing all this helps to reduce no3. Straining and feeding frozen adds less no3 than flake foods and feeding very small amounts a couple times a day is better than a larger feeding once a day.
I would suspect the crab to be your fish killer over the brittle star. Brittles mostly eat detritus and bad bacteria from the rocks but love frozen food also.