Interesting thing about GAC use with saltwater tanks is that it can be effective for months because the bacteria that colonize the surface of thr granuales can consume the organic matter that is adsorbed. A study of dissolved organic carbon concentration in several public aquaria of different sizes showed that after the addition of GAC, the DOC dropped and stayed low for months. I did an experiment where I removed three month old GAC and the aquarium water that was crystal clear looking through 4 feet of water became colored within two weeks, visible through only 18 inches of water. Not a very rigorous study, but is consistent that GAC can be effective a long time.
I change mine every 3-4 months because the bacteria growth clogs the GAC bed and slows the water flow.I never tried rinsing the old GAC and replacing it.
I can’t comment on the correlation between GAC effectiveness vs ORP value.