Generally speaking, when changing lighting, and especially when increasing the intensity, it is helpful to allow the corals to get used to the new light. The MH are a huge increase in intensity, and no doubt a change in spectrum as well. The PPE are probably not prepared to deal with so much light and are getting "sunburned" so to speak. If you only had the regular lights on for four hours, I wouldn't recommend putting the MH's on for longer than that to start.
To acclimate, they basically mean that it can help to provide some shade from the light intially, or keep it farther up and away from the tank. Also, starting with a shorter photo-period and then slowly increasing it, maybe by half-hour increments every couple/few days, until you reach your desired photoperiod would be a good way to go. I would turn those lights off and give the PPE's a chance to breath. Starting tomorrow, try setting the timer for a few hours on, then off for the rest of the day, and try to shade them a little. Work your way up slowly, and take your cues from the corals. If you see stress from the lights, back off.
PPE's aren't high-light lovers, so you don't want to toast them. Move them down and into the shade perhaps as well.
Regards,
Zack