how are you measuring pH? I agree that increasing surface agitation (try pointing your return nozzles more towards the surface of the water) to promote gas exchange is a good first step. Are you dosing anything?
Seriously, if you care about PH make sure you have an accurate probe and it is calibrated using the standard solutions, otherwise just stop testing. The only way to raise PH is to bring in skimmer air from the outside or run the intake through carbon scrubbing media. Any chemical alteration will spike KH and kill most of your corals.
If you typed PH and meant KH then get yourself a good two part solution (BRS, C-Balance, etc) and dose just enough of both parts to keep KH stable where you want it. I like 7.0 KH.
If you have this pH in a reef aquarium all of your corals, snails, clams and LS will dissolve. Your aquarium will be a large calcium reactor - your alkanity should hit the 40 KH level and so on. The probe or the calibration is wrong. No doubt. At all.