I have built one back in 1993 and I just uses stainless screws and a leach free 2 part epoxy paint think If I remember it was a Devo Bar Rust 235 and that's all.
If you have taller sides to hold large volume of gallons I would coat the entire inside with Fiberglass then coat with Bar Rust to prevent The MEPK's and styrene in the Resin from leaching out into the water. Two thin coats would be better than one think coat of Bar Rust.
Also corner supports and top supports would be best. I would supported with strapping before coating on the outside and possibly the inside.
I would coat not just the inside but the outside too.
Remember to have all your holes cut DO NOT and I stress to not cut hols after coating as this would create a weak point. I would not trust bulkhead seals around fresh holes.
Place your glass or whatever you will use for viewing inside after one coat of bar Rust or if you chose to use fiberglass. I would adhere with an Epoxy Tube sealer to prevent shrinkage. Tape or mask off the glass sand the perimeter of your Plexiglass and coat with either strips of more glass then a strap of wood coated with bar rust epoxy after in place. I would finally coat again with more tube epoxy sealant and more bar rust.
On a side note I would also use an epoxy Resin if you do use glass as the shrinkage is a lot less and the chance of any sort of Leaching is cut out. A Poly or Vinyl ester resin's MEPK or Styreen may still leach even when coated with the Bar Rust not a chance I would take if your spending this kinda coin may as well do it right.
You may not need glass at all with enough coats of bar rust it's more for long term security. The tank above has no Glass and lasted 10+ years and was given to Marco Rock he may still have it LOL