Silica sand does not cause diatoms! That is an old myth. Silica is not the same as silicates.
Silicon dioxide, also known as silica (from the Latin silex), is a chemical compound that is an oxide of silicon with the chemical formula SiO2. It has been known for its hardness since ancient times. Silica is most commonly found in nature as sand or quartz, as well as in the cell walls of diatoms.
Diatoms[1] are a major group of algae, and are one of the most common types of phytoplankton. Most diatoms are unicellular, although they can exist as colonies in the shape of filaments or ribbons (e.g. Fragilaria), fans (e.g. Meridion), zigzags (e.g. Tabellaria), or stellate colonies (e.g. Asterionella). Diatoms are producers within the food chain. A characteristic feature of diatom cells is that they are encased within a cell wall made of silica (hydrated silicon dioxide) called a frustule. These frustules show a wide diversity in form, but usually consist of two asymmetrical sides with a split between them, hence the group name. Fossil evidence suggests that they originated during, or before, the early Jurassic Period. Only male gametes of centric diatoms are capable of movement by means of flagella. Diatom communities are a popular tool for monitoring environmental conditions, past and present, and are commonly used in studies of water quality.
A silicate (SiO44-) is a compound containing a silicon bearing anion.[citation needed] The great majority of silicates are oxides, but hexafluorosilicate ([SiF6]2−) and other anions are also included. This article focuses mainly on the Si-O anions. Silicates comprise the majority of the earth's crust, as well as the other terrestrial planets, rocky moons, and asteroids. Sand, Portland cement, and thousands of minerals are examples of silicates.
Silicate compounds, including the minerals, consist of silicate anions whose charge is balanced by various cations. Myriad silicate anions can exist, and each can form compounds with many different cations. Hence this class of compounds is very large. Both minerals and synthetic materials fit in this class.
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http://minds.wisconsin.edu/bitstrea...licon.pdf;jsessionid=19hy31e505qnr?sequence=1
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