I was looking for the same info a couple days ago and found pretty much nothing on them. I am re-doing the plumbing one of my tanks since I moved and Lowes had these cheaper than a regular union of the same size.
I've never used them before but the things I like about them i it allows for some flexibility (fudge factor for me not measuring exactly correct), a little smaller outside diameter than the union, and does not reduce inside diameter since it goes over the pipe.
On the return, I felt like since the pipe is not secured tightly (to the wall or stand etc) to keep it from pushing apart I would probably just go with a reg union on it.
I decided to use them on my drains lines given there is little pressure.