I'm a molecular biologist by training, The Husband is a chemist. The test kits I've used are not going to be incredibly accurate or repeatable for several different reasons.
1) color matching - will not be accurate by eye because individuals vary in their color perception and changes in lighting will make a difference. If you want to color match you need a spectrophotometer ($$$$).
2) volume control - a drop is not a valid measurement, I need a syringe or pipette.
3) other, such as: I have the Salifert test kit for Magnesium. It uses a syringe for volume [yes!] and the instructions tell you that having air in the syringe will not affect the measurement [No!]. Air is compressible and an air bubble will definitely affect the results.
Now the important question is - how much accuracy do we really need for these tanks? Is 0.1 off on pH an issue? In my tank probably not. I'm still working with easy corals. That said, I am sending water off to Triton, mostly out of curiousity but also out of an overabundance of caution.
Do we know what the "correct" value should be or are we looking for changes? Tracking changes requires repeatability but not accuracy. A clock that is off by 20 minutes will tell you how much time has passed but it will never tell you what time it is now.
Interesting topic. Interesting rant. Lots to think about.