It's quite easy to bring your calcium levels down to be more in line with your alkalinity - simply stop dosing calcium for a few days. OTOH, bringing your alkalinity up may potentially be very easy (just dose more over several days), or possibly quite difficult, depending on the age of your tank and the number of inhabitants. If the tank is very new (<6 months) or sparsely inhabited, you may find that increasing the alk above 8 may be quite difficult because they just aren't enough dissolved organics in the water. That's despite the normal to high magnesium concentration, which also plays a role in keeping carbonate and calcium in the water from precipitating.
Temperature also plays a role in this (as do several other parameters, like pH). The abiotic precipitation of calcium carbonate is very sensitive to temperature - higher temperatures increase the rate of precipitation.