If your dosing kalkwasser in your ATO top off and running a reverse lighting schedule over your refugium, dosing small amounts of sodium bicarbonate won't have any impact on your PH. it may drop a little at the time of dosing, but it's temporary.
If your overall water pramameters are in check, PH isn't something to worry about. I never check my PH and never chase it.
I personally use calcium hydroxide (kalkwasser) in my ATO top off and run a reverse light schedule over my refugium. I dose sodium bicarbonate made into solution maybe once or twice a month. Maybe 6oz or 8oz at a time. Very little to maintain 10.5 dkh.
I don't use a calcium reactor, just kalk and occasionally baking soda. That's it and I have a lot of plating and growth happening.