Sorry for the trouble Sam.
Before anything, thank you for trying out reef-pi. Its a DIY project, hence error makes it way through various user driven processes, and the sub-optimal documentation does not help either. Lets do some diagnostics first,
1) Can you share an image pic of your setup, particularly the wiring.
2) Can you share some details about reef-pi configs, a screen shot of Configuration -> Settings UI will help as well. Check dev_mode is disabled
3) If possible , can you share the log while you do some operations in the UI ?
4) Here is the generic troubleshooting guide, check if its of any use:
https://reef-pi.github.io/additional-documentation/troubleshooting/
I'll cross check the lighting controller diagram once im home. As I mentioned, the documentation still needs some polishing, and some of it may be not correct.