Typically, 75-ohm and 50-ohm BNC connectors are made to mate with different sized cable. The center pins and outer shield crimp rings are slightly different sizes. You can get dissimilar ones to mate in most circumstances, but there will be signal distortion.
Since we're individually calibrating the sensors on each build, it *shouldn't* make a difference to you.. what won't work is if Reef-pi gets a hard-coded reference which expects an absolute mapping (say, Milwaukee pH sensor is 2V at pH 7.0), that 75/50-ohm mismatch may cause yours to be off (like 2.2V, and read as pH 7.4).
Stick with all 75-ohm if possible, AFAIK, 50-ohm BNC is really only used nowadays for older CCTV systems.
I was looking at the Vernier sensors, and if they weren't so overpriced, I'd be an advocate. They use RJ-45 with twisted-pair Cat5, which is just a way easier form factor to deal with (and I'm betting most of us here have lots of experience terminating those).