Not sure if anyone has mentioned this previously, but did this just make the whole monitor solution a whole lot easier -
https://www.atlas-scientific.com/product_pages/components/tentacle-t3.html
I have been looking at this recently. Cost is one big factor, for which I am holding off on Atlas scientific products.
From an architectural/design standpoint, I want to keep reef-pi modular. i.e. one should be able to use a component on its own, to keep thing simple and cheap. Tentacles combine 5 probes, I really dont know if I need all 5. Other than pH probe, I have heard ORP is nice to have but not really that critical (compared to nitrite or alk or ph). For temperature ds18b20 is just way better suited for our case, its temperature range, as well as simplicity of 1 wire protocol (with in-kernel drivers), makes it cheapest yet more robust (we dont need 0.001 precision probes). This is why I started with ds18b20 on the temperature controller.
That said, as I mentioned Atlas scientific probes is in my mind, particularly for pH and may be for ORP. Last week one of the local reefer (Dustin, are you around here ?

), who is also interested in reef-pi informed me he has a tentacle board, so we might have support for that sooner than later. We have to write the go based i2c driver for ezo/tentacle from my initial investigation on this board.
Personally, I would priority will be temperature, ATO and then doser. This is just reflection of my own requirements from the controller, but this is also how I can keep it tested, at least against my own tanks