What's the water level in the sump going to be at? Make the baffles a tad higher and you could easily get 12-15 gallons out of the sump. If the water level is to high for the skimmer raise it a couple inches to the correct height.
Unless your heart is set on making a custom acrylic sump. Why not just use a 20g long glass tank, go to Lowes get some glass baffles cut and silicone them into place. Your done. You are only gaining a tad over a gallon by doing 14.5"x14.5".
Yes the extra volume would be worth it plus it takes ugly equipment out of the display, gives you so many more skimmer options, gives the room for reactors and other equipment additions and finally to have a refugium if you so desire. Point being there are other benefits from a sump other then just water volume.