Hi,
Yeah, there are relations but not due to photosynthesis or respiration.
Some of the most important salts in seawater are Hydrogencarbonates and Carbonates which in aquarium keeping we refer to as KH, also have a quite important role in marine ecosystem.
A considerable part of marine pH comes from Carbonates (these compounds are well-known basic salts) and the major users of these compounds are invertebrates and algae with calcium skeletons like coralline algae, Corals, snails, and even
cephalopods like sepia have calcium carbonate skeletons.
so as these organisms fix the calcium and magnesium carbonate in the seawater the KH and pH can be decreased; we usually add KH and pH buffers together to an aquarium and also some products are said to act as both KH and pH buffers because it's hard to separate these two measurements.
Because numbers matter, we know that
more than 90% of snail shells consist of Calcium Carbonate and
almost 100% of coralline algae skeleton consists of Ca/Mg carbonate we also know that
each square centimeter of coralline algae fixes about 90mg of inorganic Carbon (Carbonates) each year and by a simple calculation we find that each square centimeter of corallines fix about 750mg of Calcium/Magnesium Carbonate (12% of the CaCO3 mass is Carbon atom so 90÷0.12=750) then we can conclude that each square centimeter of corallines fix 2mg of calcium carbonate (750÷365=2.05) each day, although this is true but not essentially in the aquarium because the efficiency of coralline growth is higher in oceans, but at least we know that an aquarium in its climax has plenty square centimeter of corallines to fix the Carbonates so it will decrease the KH then pH.
you can test this quite simply, a soft-coral tank with many corallines on the rocks will show you a decrease in KH and pH also, we know that soft corals need a trace amount of Carbonates, so where does Ca/Mg carbonates go? any carbonate-fixing creature just extracted the hydrogen carbonate from the water and fixed it to carbonate.
Sometimes pH of the tank increases to more than 8.4 and you can consider that, by having enough carbonate-fixing animals or algae you can benefit from the control of pH and just enjoy watching how fast their shells/skeletons grow.
Also, consider that keeping the corallines and snails alive is way different from keeping them in a well-managed aquarium where they can thrive.
Coralline algae can withstand pH 7.8 and KH<7.5 for quite a long time without any growth, I just talked about a well-managed aquarium with growing snails/corallines.
It may be interesting for you that Fishes are a reasonable source of carbonate production in the oceans and
they contribute 3 to 15% of total oceanic carbonate production especially fish species that nip at live rocks or any carbonate hard material in the sea, like
Ctenochaetus strigosus that can be available in an aquarium.
so let's imagine a tank with many fish and no carbonate-fixing creatures like snails or corallines the pH and KH can easily rise (although no one cares because very few people test these in Fish-only tanks regularly and also water changes just set the parameters to the standards or near them) but it happens, and method of keeping an aquarium matters.
Aquarists usually keep parameters stable by water change, but that's not the only thing that we should do;
creating a complete ecosystem DOES MATTER, and the most successful aquarists are those who are seeking to create an ecosystem not just keep things within the range (you see many aquarists enjoying their tank and some just running around to keep the things together)
so if we are looking to create an ecosystem we should always consider the Carbonate cycle, then we can achieve a beautiful tank in its climax with many creatures thriving in it.
Snail growth and production are really high but you can just see them thriving in a well-managed aquarium (
We don't talk about just keeping them alive)
My customers begin to see Turbo snail babies just after 5-6 months of keeping them (as I usually sell big-size snails they are mature) the baby snails just become the size of a pea after about 5 months. (so this means a thriving aquarium)
you may not see snail hatchlings if you have many predatory fish like wrasses.
we can discuss a lot about the kind of media that is used in the tank or carbon dioxide intake of the skimmer or photosynthesis (refugium matters) and respiration effects also, everything matters.
Here you can read about friends' experiences with high pH and ask them also; pH higher than 8.4 is quite regular in a professional tank and many things can cause this, like reactors or the amount of additives that someone uses or a refugium. (they have many carbonate-fixing creatures and add plenty of hydrogen carbonate so they have a pH higher than 8.4 and enjoy watching their aquarium thriving)
any pH between 8.1 and 8.6 is considered to be really good.
but the short answer is yes the KH and pH decrease due to shell/skeleton making of creatures like coralline algae or snails.
check the hyperlinks to see the references and for further reading.
Bests,
@Daddy-o Could you please share your valuable experiences? appreciate