The way I used to do it when setting up new tanks for customers is you stop the pump, add water until it's as high as you feel comfortable with (say, when you have a power outage), and then kick the pump on. Mark that running level on the sump as your high water level. You know it won't overflow if the pump cuts off.
Your low point will just be a little above where the pump starts sucking in air. As far above that as you feel comfortable. Now you know the two levels you need to stay between with top-offs. Top off with RODI.
If you need to lower the salinity in your tank, just take out some salt water and add some RODI. You can estimate how much to remove this way. Say you have 100 gallons at 35ppt salinity. Let's see how a 5 gallon water change would work out:
35 ppt x 95 gal = 3325 (we use 95 since this is how much salt water will be left after removal)
3325 / 100 gal = 33.25 ppt (we use 100 because this will be the new total volume)
Or just 35 x 0.95 will be the new salinity. Whatever makes the most sense to you.