RO water will be 90 to 98% pure with a properly functiioning system. RO/DI will be 100% pure as it takes the deionization process to capture the remaining contaminants the RO membrane and carbon are not efficient at.
New saltwater or sea water will have somewhere over 32,000 TDS TDS is not a measurement of anything specific, it includes everything electrically conductive present in the water. 0 TDS means there is noting left but pure water molecules so you are starting from ground zero when you add your salt mix which should contain everything you need and in the proper amounts.
To test an RO system with a handheld TDS meter you need two TDS readings, the tap water TDS and the RO only TDS straight from the RO system, not from a pressure tank or other storage container. Take the tap water TDS using a meter and a squeakly clean clear glass drinking water glass washed by hand in very hot water so it has no soap residue, dishwasher spotting agents or hard water spots. Record the reading then triple rinse both the meter and glass with distilled or RO/DI water so you are getting an accurate reading and take the RO only TDS and record that reading. Triple rinse the meter and glass and put the meter away clean and capped and the glass upside down so it stays clean with no salt spray of dust.
Now, take the tap water TDS, subtract the RO only TDS, divide that number by the original tap water TDS and multiply that by 100. As an exampls say your tap water TDS is 250 and your RO only TDS is 10. 250-10= 240, 240/250= 0.96, 0.96x100= 96% rejection rate or removal efficiency. 95% is about the minimum efficiency you want to see from a RO membrane and it could and should be more like 98% efficient with a good, new membrane.
Adding a good 20oz, 10" vertical refillable DI filter on the end should get you to 0 TDS. This is where you want to be for a reef system. The more efficient the RO membrane is the longer your DI cartridge or resin refill will last and the better it will work. For every 2% efficiency loss below 98% the RO only is, it cuts your DI resin ife in half so starts costing more than an efficient RO membrane upgrade would be.