There are always a lot of questions regarding which RO/DI setup do I need, how many stages, how do I know when to change filters/membranes, I’m getting a weird TDS value, etc. Hopefully this clarifies a few things and helps some of you out one day. My first recommendation would be to find the...
www.reef2reef.com
Not sure if got the answers you want in this,but maybe give this a read.
Seems like you getting nearly 50% reduction after your membrane so something clearly up.
My first thought,was the membranes fully inserted so the water going through the membranes and not bypassing,second thought was your in-house carbon 4 foot thing,its few years old you say but is this letting any fines through or something like this.
Then 3rd thought was what membranes you actually using,are they good ones kind of thing and then was have you got correct restrictor in,and i read often 80-90 psi is a good psi to aim for so if you got the booster pump maybe give that a try to just install on rodi unit.I'm a plumbing and heating engineer but not a rodi expert as only fitted and used my own and fit a few just small ro units under a sink in past.
So no expert as I say as knowledge on rodi units pretty limited tbh.
Good luck and hopefully you get to bottom off your problem.