The first pint or two out of the good RO line is going to be high in TDS if the RODI unit has been sitting for a day or more, due to what's called TDS creep. Ideally you should have a valve between the RO and DI filter to allow the first quart of RO water to be collected and discarded. You can run it through the DI however it will use up your DI resin much faster. I usually collect a half gallon or a gallon of just plain RO then switch the valve to run through the DI for the aquarium use. That RO only water is really good for houseplants and coffee machines
So if you are talking about water that has gone through the DI while flushing the RO membrane then yes it is fine for the aquarium. BTW you shouldn't need to flush the system every time you use it. Especially if your prefilters are clean and your source water is decent.