RO without DI is 90-98% more pure than tap water. RO basically acts as pretreatment for DI in our hobby. If the system is in good shape and has an efficient RO membrane that is functioning properly it may be worth picking up and adding a DI filter to.
One thing I will caution you on though is often it costs more to upgrade a used system to reef quality than it does to purchase a new reef quality RO/DI for around $112. You can almost guarantee the used system will require a new sediment and carbon block filter at a minimum and in many cases a new RO membrane also if it has been sitting around for long or has not been taken care of properly. Thats close to $75 for high quality replacements right off then add an inline pressure gauge and add on DI and you have probably exceeded the new cost.
If you have more info on the system it would help you make your decision. What brand and model, how old, has it been maintained properly, the tap and RO only TDS numbers it has been producing historically and how long it has been out of use. Was it stored with water still in the unit to keep the membrane wetted and was it exposed to temperature extremes and bright direct lighting?