Wow are you scratching your head yet OP?
Arm and hammer baking soda is the same stuff you buy from BRS, sodium bicarbonate. They are interchangable, both basically the same with the BRS being "pharmaceutical grade"(if you believe that sort of marketing), and Arm and Hammer being, well food grade. You decide which to use, but both are the same.
You really need to google "Randy's DIY 2 part" to understand how to make the alkalinity part.
If all this is confusing the heck out of you, just buy the BRS chemicals and use them for now.
Then once you test, you take the number you have, and match it to a typical reef parameters.
Alk 7 to 11 DKH(Most keep this in the 8.5 range for a margin of error)
CAL 420 ish
MAG 1250
If your tanks numbers are lower then these values, then use this calculator to figure out how nmuch product to add:
You can choose Randy's recipe 1 for the BRS chemicals(they based their formulation on Randy's DIY 2 part).
Easy peasy..... I know it sounds daunting, but once you wrap your head around it, it's actually pretty easy.