Yup, physics defying magic, lol. At 40 psi for a 90gpd op will have continued problems or will be changing cartridges and membranes why more often then need be. You were the one who said spectra claims 40 psi minimum, so what happens when filters start to clog, umm, psi goes down below their minimum claim.
If you’re gonna need carbon to remove vocs, than you need catalytic carbon, and would say the house’s water smells, and all there neighbors would be aware of it. It’s also usually only needed or useful in filters with hi flow, which RODI units are not. And of course they won’t damage the membrane anywhere as much as chlorides and fluorides will.
They also will not show up on tds reading , just as chlorides and fluorides won’t, and even s catalytic carbon might not get every or all of it. Knowing that many, or most vocs will dissipate at room temperature, and/or with aeration, regardless should really test water and determine type and amount before deciding that carbon is enough, and would be more concerned with showering or drinking where the water doesn’t have time to sit and aerate as it would in collection container, or fish tank.
With that said, vocs are much more a problem with city water, and on well water he almost certainly does not need carbon block.