Using your handheld TDS meter and a squeaky clean clear glass drinking water glass washed by hand in extremely hot water so it doesn't have any dishwasher soap residue or anti spotting agents to skew the readings take a sample of your tap water and insert the meter letting it stabilize. Record the reading, triple rinse the glass and meter in RO/DI or distilled water then take a sample of the RO only water directly from RO by disconnecting the line between the RO and the DI to fill the glass. Again, insert the meter, let it stabilize and write the reading down. Those two numbers are used to calculate the rejection rate but while you are at it do another triple rinse and sample your RO/DI directly from the unit, take the reading and do a final triple rinse so both the meter and the glass are clean for next use.
Take the tap TDS number and subtract the RO only TDS, divide that number by the original tap TDS then multiply it by 100 for your rejection rate. An example using my readings of 560 tap TDS and 2 RO TDS goes like this: 560-2= 558, 558/560= .9964, .9964x100= 99.64% rejection rate. Out of a 6+ year old RO membrane that has never been changed is pretty good. Dow Filmtec membranes should be somewhere between 96 and 98% off the shelf but not always and when tested most come in around 96-97%.