Yeah my guess is (for future readers to help) either the return flow from DT to sump is so slow that the RO from ATO is dropping salinity OR you are doing something different when measuring salinity between the 2 samples - i.e. perhaps using a different syringe for DT than Sump and the syringe for DT has some residual salt in it, increasing the salinity. I had frustrations in the past trying to match my DT with my QT, only to realise it was due to using different syringes (as you need to isolate all QT equipment). A few squirts of RO through both syringes and they matched again from the same source.