I'm not familiar with those pumps, but simply turning one on for awhile, then off while the other is on, should be doable with an OSC command.
For the first powerhead, you might have it programmed:
Fallback ON
OSC 000:00/005:00/005:00 Then ON
For the second one, it would be:
Fallback ON
OSC 005:00/005:00/000:00 Then ON
What this would do is turn the first pump on for 5 minutes, then stop it and turn the second one on for 5 minutes, and so on indefinitely.
This can be modified for longer or shorter durations, although the total minutes in each line should divide evenly into 1440, for it to restart smoothly at midnight every day.