You don't change the ORP probe name to pH and calibrate...it does not work that way...
Yes connect your 2nd pH probe to the ORP/pH2 port and then go to the display module and do these steps:
Main Menu> Setup> pH Setup> pH Enable (now it will display pH first and use the arrow pad up & down to select pH2 and then enable this probe)...
back out of the programming to Setup page and then do these steps:
Setup> ORP Setup> ORP Enable (now select the ORP probe and then disable this probe)
again back out of the programming to Setup page and then do these steps:
Setup> pH Setup> pH Calibrate (now it will display pH first and use the arrow pad up & down to select pH2 and then calibrate this probe remember to have the correct calibration fluid on hand because for ca reactor you would need 4.0 & 7.0 and of course for tank pH you would need 7.0 & 10.0)
Last step is to rename the probe and to do this just go back to the Setup> pH Setup> pH Name (now it will display pH first and use the arrow pad up & down to select pH2 and then rename this probe)...
This can also be done through the Classic Dashboard