Small closed systems are prone to fluctuations. that is what makes nanos so hard to keep delicate species - don't panic that'll just cause more fluctuation
The algae may have had an effect in that at night yes they do release co2, as do all of the critters and even the bacteria in the tank, the larger your bioload the larger these may become
An interesting but often overlooked culprit in pH drops at night in the cooler months, is that our houses tend to be more closed up and indoor levels of co2 are higher in general. Higher co2 levels in the house air will add co2 to the tank and lower pH
I wouldn't do anything drastic. just watch it for a few days and see if it is the norm for you tank
Some find they need to draw air from outdoors in the winter for their skimmers