Most jawfish are rather difficult to sex. And they are gonochorous = don't change sex.
Of those species where the male keeps the eggs in his mouth (not all Jawfish are mouthbreeders!), males often are larger and have a slightly longer and wider mouth/head.
With BSJ and their close relatives (who are not mouthbreeders) it is the other way around, males are smaller than females, more slender build, and have a narrower head (which still might be a bit longer).
There are a few other things someone could sex them by but none of those is practical (fish stores generally don't like it if you anesthetize their fish to examine them under a microscope) or easy for the average reefer.
The only Jawfish I know of to be easily sexed by coloration is
Opistognathus randalli where the females have a black spot at the front of their dorsal fins that males don't have. Top male, bottom female:
I generally go more by gut feeling than science when trying to make Jawfish pairs.