Don't try to do anything to get it to molt, molting is tied to egg maturation so the night it releases the eggs it has (provided they are fertilized and come to term) will be the night of the next molt. Typical incubation time is about three weeks, and if you have more than one shrimp, the fertilization of the next batch of eggs happens right after the molt, so they can appear to continuously have eggs.
Eggs start out greenish/yellow, turn yellow, then in the last few days before hatching become sort of a tan to white color. The day of, they will inflate somewhat and usually are visible just barely sticking out from under the shrimp, and they'll probably be released just after dark.
Also worth noting, in a tank with reasonable flow, you'll have all of 5 minutes or so if you want to save any of them, so if you want to see them at length, turn those pumps off for an hour or so the night of around dark.