I was thinking about building a square skimmer with baffles to reduce the flow
Baffles give you a longer path, but may increase velocity. Increased volume is what you want if slowing the flow is your goal. (Of course, you can do both.)
Think of a winding river (fast but long) vs the Mississippi River (slow and direct). Both could be the same gph. To complete the example, you can also make a "winding Mississippi" if you want.

I suspect you may get excessive air buildup within the baffle system unless velocity is pretty high to carry bigger bubbles through to the reaction chamber/neck of the skimmer.
The bottom line IMO is to keep it simple and just make sure your design is matched to the size of pump that you want to run. (4x display volume is a good rule of thumb for flow rate of both sump and skimmer.)
I think if I were going to DIY I'd knock off an AquaC. Extremely simple designs that are highly effective and do not require a special kind of pump. (I personally like to remember that the first skimmer was a lowly airlift tube in an undergravel filter…and it worked well. LOL)
-Matt
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ratios end up the about the same too.

