If my rock was to leach phosphates would they already be detectable? If so what would be a concerning level?
yes, it would be detectable. .25 and above I suppose would be worth looking in to. As it may slightly increase(or decrease too as the bacterial cycle begins). at .25 a ploy pad or some gfo would probably suffice. at that level a refugium has actually worked for me in an established tank.
The concerns voiced by others is the organics on the rock will dissolve and increase the amount of Po I believe in conjunction with what is(may be) bound to the rock.
Please check out Rand Farleys Parameters recommendations. But know that from species to species this changes. You'll hear the saying "Zoas like dirty water" so higher nutrient Po and No, and everyone has their own secret recipe. So really it also matters from species to species, and parameter recommendations are just that, to set a zero ground to start with. Zero Po and Zero No are actually bad for the coral. detectable amounts are actually good.
Many now esp here on R2R are quite flexible on the numbers and as they gain experience, dont check

. Its a good way of learning though and knowing whats going on and tracking is how you gain experience in it.
I never really checked Po on a cycling tank when I was just starting, dry or live. I never experienced and extended ugly phase either. I only lost one tank to high po(1) and no(20-40?) and it didnt crash it just got cyano bad and I rehabbed it with good high light, a little peroxide, a scrub brush and a refugium. Its now sitting behind me and is fine. and i didn't lose coral or fish or my nem.
I do recommend a strong bacterial cycle and diversity as for me Im pretty sure that was my only accidental secret. get the nutrients processing. I just did my first dry cycle in a long time with dry sand and rock, with limited bacterial sources. it went ok. got diatoms and some algae a little green stuff that went away. Ive never had diatoms before.its been ugly a while too. None of the coral i put in died though. I only tested Am and confirmed the cycle with addition of Am. But that was an experiment. Kinda yucky, I dont know why folks do it like that.
IMO is now get as many strains of bacteria as you can in there. there seems to be plenty of food. That food is Po, fwiw

(its in the second article)
Parameters
http://reefkeeping.com/issues/2004-05/rhf/
Phosphate
http://reefkeeping.com/issues/2006-09/rhf/