For the grounding probe, here's an example: I'd definitely put one in your sump. If you have any electrical components in your DT, I'd put one in there too. However, if you just have electricity outside the DT (eg exterior motors like with a vortech circulation pump), then you don't need to worry about that in the DT. Basically, you want anything that can generate voltage in the tank to be able to "reach" a grounding probe EVEN IF THE FLOW IS OFF. Saltwater is a great conductor, but electricity can't travel through an air gap in an overflow when the flow is stopped, for instance.
For darkening panels, you'd want to do that to the two internal glass dividers and back wall section of where your sump rocks are. Leave the front glass panel clear so you can see what's going on. Easiest way at this point is to drain everything and then superglue some aquarium background () to those panels. You could also use a black non-toxic paint, but that would've have been easier before gluing in the dividers. Just keep the height of your light low in your new refugium area so little light spills into other compartments. In your setup, I'd highly recommend getting a submersible refugium light. This definitely helps minimize light leak and you don't have to worry about a regular light getting wet. I put this one in my refugium, but you can find much cheaper ones on Amazon (
https://www.bulkreefsupply.com/waterproof-10000k-led-fixture-8821-00-tunze.html). Just make sure the description says it's suitable for growing things in a refugium---and not just an ornamental light. You definitely don't have to spend a lot to get a good refugium light these days.