TLDR answer: In your example, dose your additive to a level below what you suspect the volume is to be safe. Raise dosage over time if you can measure the additive based on testing (ICP or other).
Longer answer: If it were me, I would do my best to protect the health of my system and avoid as much of a change as possible. If you have a digital salinity pen, this would likely be the best method. Take a base measurement, then add enough RODI to decrease salinity that can be measured. So if the salinity pen measures starting salinity at 35ppt, add enough RODI until the pen reads 34.5ppt. Plug those values into the calculator and the approximate volume is shown. I entered this example below, 35ppt starting, 34.5ppt after adding RODI, 2 gallons of RODI, pen measures in 0.1 units of measure. The calculation is that this is a 138 gallon system.
As the tool states in the fine print, a larger water sample is better to ensure an accurate calculation. But who is going to add that much RODI and risk the health of their system? Not me!