Several issues arise relating to the depletion of the DI resins that aquarists need to be aware of. Primary among these is that when a DI resin becomes depleted, that does not simply mean that the water passes through just as it came from the RO effluent. It may actually be much worse from an aquarist’s perspective. The reason for this is that while the DI resin is functioning properly, all ions will be caught. But when it is depleted, not only the new ions are coming through and might show up in the product water, but so are all the ions that ever got into the DI resin in the first place. The total concentration of ions coming out of the exhausted DI resin will not be raised as compared to the RO's effluent, but which ions are released may be very different.
In the DI descriptions above, I did not address the fact that some ions will show a greater preference for attachment to the resin than will others. When the resins are not depleted, it does not matter what the ions’ affinity is, as all are bound. But in a depleted scenario, when there are more ions than ion binding sites, those with a higher affinity for the resin will be retained, and those with a lower affinity will be released. It turns out that silicate is found at the lower end of affinity for anion resins . Consequently, if the DI resin has been collecting silicate for a long period and is then depleted, a large burst of silicate may be released.
Perhaps even more of a concern is ammonia. In a system with chloramine in the tap water, the DI resin will serve the important function of removing much of the ammonia produced by the chloramine breakdown. Ammonia has a poorer affinity for many cation-binding resins than do many other cations (e.g., calcium or magnesium). Consequently, when the DI resin first becomes depleted, a big release of ammonia from and through the DI resin is likely. I recently had a DI resin become depleted, and the effluent contained so much ammonia that I could easily smell it.
