KH, Ca PO4, NO3, Mg-Those are all I ever use and KH being the most common-but on the KH I use the acid tritration method with sulfuric acid
You can buy 0.1 N Sulfuric acid standard used as the titrant from:
http://www.grainger.com/Grainger/items/4YNA6?cm_mmc=Google%20Base-_-Test%20Instruments-_-Laboratory%20Supplies-_-4YNA6[/url] also sells 0.1 N sulfuric acid standards.
It may be best to calibrate your pH meter using a 4 & 7 standard before you start the test.
Easy part; Testing
Now take a sample of your aquarium water, you can use any volume but I like to use 100ml because my pH meter sits nicely in the cup without me holding it at this level. Stick in your pH meter to your sample. You should get the same reading you do when you stick it directly in your tank. If not start over with a clean sample container. Now draw up some 0.1 N HCl solution in to your 5ml syringe. And start dropping into your sample 0.5 mls at a time and watch your pH meter. You are adding a strong acid so your pH should fall rapidly. Once your pH hits 5 start to slow down and add a drop at a time until your pH hits 4.2 . The reason we are shooting for 4.2 is because this is the point where all available carbonates have been converted to carbonic acid. You would think this would be pH 7 but it's not as carbonic acid is a weak acid and you have to really saturate it etc. Anyway, once you have reached pH 4.2 you are done and now can calculate your total alkalinity.
Alk mg of CaC03 /L = A x N x 50,000 / mL of sample
Where A = ml of acid added
N = normality of your HCL
So if you added 4ml of 0.1 HCL before you hit a pH of 4.2
4*0.1*50,000 / 100 = 200 ppm CaC03 equivalents or your total alkalinity is 4 meg/L (mg/L / 50 = meg/L).
The above information was taken and corrected from this thread:
http://www.reefcentral.com/forums/sh...ion+alkalinity
Randy provides further details in this article:
What is Alkalinity
Chemistry and the Aquarium: What is Alkalinity? — Advanced Aquarist | Aquarist Magazine and Blog