I have a fluval 12 gallon tank that loses about 20% of the water due to evaporation a week. Could I just top off the 20% with my RODI?
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A bit more clarification may be needed... It seems that you are thinking with the loss of 20% of your water if you top it off with RO/DI instead of saltwater would that work.
First thing is that salt does not evaporate. So what you are losing is only water and needs to be replaced with only water (no salt). When water evaporates you need to only put RO/DI back in to get it up to its normal level.
As for a water change. Yes you still will need to do them. Make sure your water is at its optimal level before removing any water to do the water change.
You will want to remove your (whatever % you intend to change) tank water and then replace it with fresh salt water. It is ideal to mix the new salt water for at least 24 hours prior to changing it.
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