Well coralline algae just like anything else is going to lower calcium and alkalinity together. Corals, clams, coralline.. all use alkalinity and calcium together to generate calcium carbonate.
So here’s a possible scenario:
You measure the following
8.0 Alk
380 Calcium.
You then dose AFR, and immediately test
8.0 Alk
400 Calcium.
Next day you test again:
9.0 Alk
390 Calcium
At this point what has happened (assuming your tests are perfectly accurate) is that the AFR raised your calcium immediately, however the alkalinity was still locked up with the formate. The next day the formate metabolized unlocking the alkalinity; but both calcium and alkalinity also were used up due to calcifying organisms. (My numbers are probably not completely accurate, Randy’s better with the exact math, but the basic trends are correct)
So with AFR, you just have to test and make sure things are “about right”. Even if you test off calcium, usually that seems to fluctuate more than it does due to test error.
It’s why I wouldn’t advise using it for sensitive stuff like Acropora. However it seems okay for your tank livestock. (I use it in a tank with softies and a few stony coral, and I don’t worry about)
So just get your numbers about where you want them, then dose and keep track of the trend over several weeks. If it continues in one direction increase or decrease. As things start to grow and change you’ll need to change dosing as well.
Ultimately don’t worry unless you’re seeing large excursions.
If you’re more OCD like me or want to keep things super stable for Acro or something, then you might want to change away from AFR.