I think you got some of this advice in your other thread too.....but I'd skip the baking on reef-oriented grounds in addition to the police-avoidance reasons aforementioned!
I think you're also seeing an association of equivalence between DIY two-part and products like Brightwell's.
They are similar. And they do function about the same. But they are not equivalent.
Road salt is vastly different in purity than what you'll find Brightwell or any of their competitors - including BRS - using in their products. Baking soda too. This is why Brightwell and any of the better products (again, including BRS) cost more than road salt!
Also, Brightwell tends to offer their alkalinity products as blends of baking and washing soda, as well as some borate salts. As a result, they tend to be a bit more neutral in impact to the tank. This may be useful to some people, but I've had the best luck with plain baking soda - it's (very) slight and temporary pH-lowering effect works against (or doesn't encourage) calcium precipitation during dosing.
So, are the DIY ingredients "good enough"? Based on my experience and others, they seem to be. (A good water change routine is pretty mandatory as a compliment, especially at higher dosage rates.) But, if I weren't as budget-limited as I am, I think I'd still be using a commercial calcium additive like Calcion-P along with baking soda. Probably a commercial Mg additive as well, but that's usually a very minor expense either way to you.
Hope this helps!
-Matt