Here is how I see it. First when you add new dead or live rock that needs to be seeded. It has no beneficial bacteria yet. Your old live rock is ONLY ready now to filter 8g tank. So you would only keep up the filtration of what you have in the 8g. When you add new live rock especially 5x as much as what you have now. You best believe it will cause more than a mini cycle. That will be the full on cycle. Here is the thing.
Ammonia will be on that new live rock possibly. Like sponges and critter. Those need to be handled. Basically your die off. IF there is any. You don't want to chance it. Instant gratification in this hobby is not something that comes without paying the price.
So you seed your LR with some kind of kick start. I prefer a table shrimp. Lightly ghost feed. Every other day with what you feed your fish normally to beat up your tank and KNOWING how to breakdown what will be added in. I have a problem with common sense. I use it. Common sense says if there is all these bottles out there of instant gratification of bacteria. Why do some work and some don't? They are supposed to be just bacteria right. So there has to be some kind of underlining we don't know about that is not being said and that is why you go with what is best not instant.
Nitrites turn ammonia into nitrates. Anaerobic bacteria is what turns your nitrates into a gas form to float up out of your tank. If you do not give your tank the time to get that anaerobic bacteria to populate. The most important thing as I see it. You better be ready to do substantial amounts of water changes to fight the nitrate battle, because it has no other means or ways of getting out of your tank.
So to answer your question. Yeah it probably could be done with instant ocean and a few other chemicals. Would I advise it. 100% not. You run the risk of to many thing, because you are upgrading to an unestablished tank. Like filter and LR for starters. If it was a downgrade. Then I could see the possibilities of turning 40lbs LR into 5 x 8g tanks.
I went from a 20g(1year) to a 40B(last 3 months)