Randy, I have a little question...
here in Italy, may tell that using only baking soda (NaHCO3) in a long time could cause a ionic unbalancing and a lower Ph condition.
That because are missing other carbonate and borate, that are included in many commercial balling kh powder.
Are you experiencing this effect? or is only a reason, try to sell us at 12-15€/kg a powder that we can buy at 2€/kg food grade..
thanks
The carbonate comment is just wrong. The exact truth is that the carbonate concentration is exactly determined by the pH and the carbonate alkalinity. It makes no difference if the supplement used to get there is bicarbonate, carbonate, or hydroxide. All end up being the same when the pH is the same. This is attained by CO2 entering or leaving the system. Taking hydroxide (as in limewater/kalkwasser or in my newer DIY two parts) as an example, we find the hydroxide readily combines with CO2 to form carbonate:
2OH- + CO2 + ---> CO3-- + H2O
FWIW, many big name reefers have not understood this process and have made incorrect claims about reef tanks using limewater/kalkwasser as being deficient in carbonate. That is just wrong.
The same happens in reverse dosing bicarbonate, which quickly equilibrates to form some carbonate and there's no deficiency of carbonate:
2HCO3- <--> CO3-- + H2O
As to the borate, yes, this method will deplete borate (and potassium and everything else not added). Each time you correct for the salinity rise from the sodium and chloride that coems from using just sodium carbonate/bicarbonate and calcium chloride, everything declines. That is why two commercial two part systems (and balling) include these other things.
A DIY two part that uses nothing besides sodium bicarbonate and calcium chloride is not a perfect system for this reason.
As to borate specifically, I do not think it has any clearly demonstrated biological benefit in a reef tank, but a few random organisms seem to use it and maintaining it at normal levels seems a fine plan. It is easy to dose, but harder to measure unless you use ICP.
FWIW, I never added any at all, and water changes were adequate to maintain it at NSW levels (actually a tad above).