You have to be able to control the flow through the UV so that it is slow enough for the bacteria to spend enough time exposed to the light on each pass-through in order to be killed. (Your UV instructions should tell you what amount of flow should pass through it.)
If you put the UV in your main return line would likely mean having to restrict the flow of your return pump.
If you run a tee off of the return line, then go through the UV, you can't have another tee back into the return line because the main flow from the return pump would not only try to go through the first tee that feeds the UV, it would also try to flow through the second tee into the 'exit' end of the UV. In essence the return pump would try to feed the UV from both ends ... like feeding water into both ends of a straw at once.
Basically, you have 3 pluming options that will allow both the UV to work ... e.g. sterilize the water ... properly and the return pump to return water to the DT without being limited by the UV:
1) The diagram I showed you earlier which tees of the return line, through a ball valve to slow the flow through the UV, then, out the UV directly to the DT. Yes, this would mean two returns into the DT - one from the return pump, the other from the UV.
2) What vetteguy53081 recommended: A dedicated pump that pulls from the first chamber of your sump, passes it through the UV, then out into the return chamber of your sump. Just make sure either the pump is adjustable or you have valve between the pump and the UV so that you can adjust the flow through the UV.
3) A separate pump in your return chamber that feeds into the UV ... which then feeds into the DT. This is probably the most difficult to set up since you basically two return pumps running two return lines from your sump.
This article explains the hows and whys a whole lot better than I can. The entire article may make your brain explode (I know mine pretty much did). It has a LOT of info in it ... to the point of overload. But the section next to this image in particular may be very helpful: