As best I can tell, the relative effect on nitrate/phosphate consumption is the same with vinegar and vodka.
I think the relative effect has more to do with where it gets consumed (inside live rock or sand vs on oxygenated surfaces or in the bulk water column) than the nature of the organic itself.
i use vinegar for two reasons:
1. It seemed to cause less cyano in my tank when I first started messing with organics.
2. It is used by a very wide range of organisms (not just bacteria) so may have less chance for accumulation than vodka) and may even be beneficial for higher organisms which take it up (corals, sponges, etc). In some sense, it might be considered a bit more "natural" than ethanol from vodka as acetate makes up a bigger portion of the natural cycling of organics in the ocean.