I'm curious why one would use a dialysis membrane in this situation. I see no potential benefit and some drawbacks.
Have you ever looked to see what is exported using this method (say, by analysis of the removed fluid)?
I have two potential concerns.
1. Whether the exported fluid has had sufficient time to fully equilibrate ions across the membrane.
2. Whether large molecules (organics such as proteins and associated bound metals and other ions ) can be exported through the membrane.
Thanks for any insight in choosing this method.
Great questions, Randy. I feel like I was just called on in class by the professor. Gulp.
Why? Just for fun and something to talk about with other nerds. Kind of like a triple carburator on an old Ford Galaxie.
And... compared to making an awc system, the only extra cost is the dialysis membrane, and one extra pump to run the brine. This deletes the need for properly made saltwater - which saves space and effort. I do admit... I could use brine infusion instead of salt water with an AWC and omit the membrane and one pump - but I borrowed the idea from the Seavisions dialysis system - and this is where I am in my journey.
Potential benefit = for anything smaller than 400 kDA (or whatever the pore size of the membrane), there might be preferential removal of anything not in the salt mix - over time. This might include phosphate, nitrate, ammonia, any toxic metals, certain drugs, small organic toxic compounds (organophosphates for example). So maybe, for every 50 lbs. of salt I put back into the system, I can accomplish the same thing as 100 lbs. of salt consumed doing water changes - with regard to this group of dialyzable / ions and other molecules. Since my system is 1400 gallons, reducing the salt budget and how many pounds of salt I have to haul into the basement (by half for example) would a considerable accomplishment. This is the claim by the dialyseas (tm) company - seavisions - who has been selling a version of this for decades. I quote from the diayseas website "removes waste by minimizing original water and salt loss". After experiencing mysterious acropora declines over the years... any potential help in clearing out mystery poisons from the exterminator or whatever else... helps me sleep.
Here is an article outlining an analysis if the exported fluid.
https://reefkeeping.com/issues/2006-04/pr/index.php
It seems to support the preferential removal of nitrate and phosphate. Hats of to Ken Feldma. Seemed to conclude a solid "maybe" that it works as advertised to preferentially remove certain ions and molecules.
Large molecules cannot be removed by dialysis. So, I do wonder... what is stuck in my tank that is not removed by dialysis, mechanical filtration, ozone, UV, metabolism (fish, invertebrate, coral, algae), carbon... or other degradation? Something that can only be removed by water change and nothing else. I do wonder!
Future experiments.
1. how does the flow rate effect equilibrium? I suppose I can run the flow at different rates, and different pressures and check the resultant product salinity - to see if there is a difference. Does the export salinity rises with slower flow rates? What about if I pause the system for an hour, then analyze the flush?
2. what is the least amount of dialysis / salt, that I can get by with while maintaining normal triton tests? right now, four bags per month (enough to make 200 gallons of salt water). Perhaps, a 15% monthly water change equivalent. not exactly a miracle - I admit.
Appreciate comments and discussion.