FIRST OFF.... there is no comparing a natural reef to our "glass boxes".
Filtration - Nature: bazillion gazillion gallons of SW flows thru natural reefs, sorta like us doing a 100% WC every 30mins. cant compare
Filtration - our glass boxes: skimmer exports unwanted elements out of our water AND OXYGENATEs our O2 levels. Chateo is a great choice in sump to eat NO3 and PO4. Carbon dosing super charges GOOD bacteria to outcompete bad bacteria. Weekly WCs is also an underappreciated filtration method.
I personally do all four methodologies and cant wrap my mind around ppl who argue to not use all four.
Sunlight versus Artificial: Sunlight is full spectrum as charted here:
In nature, SW filters out most of the UV and red/infrared the deeper you go..... leaving a light wavelength at around 420-460nm
* note "visual light" range above to our eyes is White light coming at our eyes.
10yrs ago it was a T5/MH world... but LEDs changed to world of reef being able to hone in on peaks.
Me personally, I took eBay Chinese fixtures and resoldered all the diodes. I'm 30% 420nm - 30% 460nm - 20% 540nm green - 10% 390nm uva - 10% 660nm red
Coral health - I'm a huge believer that corals exist at certain DEPTHS for a reason, mainly bc of the light wavelength. the deeper you go the more every nm gets filtered out but 420nm.
You should know at what DEPTH the coral you want to keep thrives at, and replicate that, Mixed reefs can be successfully kept but certain corals wont fully display their color bc they are exposed to a nm wavelength they naturally aren't use to.
Take a deepwater chalice and throw a lot of full spectrum white light at it, it might lose color, possibly brown out, bleach out.
Fish health: it's all about not over stocking the tank. Yes we see schools if fish on Animal Planet but it's the Ocean where a bazillion gazillion gallons of SW is sweeping away toxic elements that our "glass boxes" cant even begin with competing with.
Managing food is ultra important. Throwing in food that is NOT consumed in 3mins and still floating around will turn toxic poisoning that tank. I try to use a strict 3min feed amount.
Water chemistry: Triton and all these dising methods are a good thing but a good old WC regiment is best IMO. A great salt is going to have all 70+ major, minor and trace elements in an ENGINEERed formula. You'll never see a Iodine overdose in WCs but you will see it if you become the Mad Dosing Scientist trying to make the perfect "soup recipe"
Hope this all helps with some insights over 15yrs
.