What would prevent PO4 reduction?

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clm65

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I am dealing with high nitrates and phosphates, which I am currently attempting to fix with nopox (I have another thread on this forum that covers that). I did a water change yesterday and saved some of the water to do a little extra testing.

So I put 1 quart of my old water in a container. According to a recent ATI ICP test, nitrates in my water are >400 mg/l, and phosphates are >2 mg/l. I didn't check the nitrates in the cup of water, but I did test it for phosphates using a Hanna tester and got 2.17 ppm, so I don't expect any significant difference in water parameters from the 3/31/19 sample date for the ICP test and what I have now.

I decided to see how effective Phosphate Rx really is on my water. The instructions say 6 drops of product in 10 gallons of water will reduce phosphates by 0.5 ppm. So in my 1 quart water sample, I would need a fraction (15%) of a drop to get a 0.5 ppm reduction. It would seem logical that 1 drop would have a significant impact. I added one drop, but didn't see any clouding. So I added another drop, and one more for good measure. I then transferred the quart of water back and forth between two cups a few times to make sure there was adequate mixing, and then poured it through a 10 micron sock to filter out any flocculent. I then tested the water again, and phosphates were 1.79 (0.38 ppm reduction). That is quite a bit less than expected. I know I am supposed to wait 24 hours before re-test, but I was a little impatient. I can retest tonight and see if it changes, but since it is just water with no phosphate-saturated rock or sand, I don't really expect much of a difference.

TBH, one of the reasons I wanted to do this test is that I didn't feel I was getting the expected results in the past when I tried Phosphate Rx and Phosphate-E to lower phosphates. I figured there was so much bound up phosphate in the rocks and sand that the phosphates quickly recovered. But in this test, there really shouldn't be a source of phosphates. My calcium and alk are both very high (641 mg/l and 12.51 dKH, respectively). Is there some sort of relationship there that would inhibit phosphate reduction? I have read that you need some phosphates to reduce nitrates, but not sure if anything is needed (or not allowed) for phosphate reduction.

I do plan to keep going with nopox on the tank for a while and see what kind of progress that makes. But just wanted to make sure there is not something else I should be looking at that I might be missing.
 
So tonight after work I re-tested the water sample and got what I originally expected to get - 0.0 ppm phosphate. And there was noticeable white fluffy masses on the bottom of the cup. I thought that the reaction was supposed to be instantaneous? Yesterday about 5 minutes after I added the drops I poured the water through a 10 micron felt sock. Apparently the Phosphate Rx had a delayed reaction and went through the sock?

Any thoughts or opinions?
 
Phosphate Rx/lanthanum chloride is very effective in “removing” PO4 by binding to it (the white clouds you see) and it IS instantaneous. I’ve poured the commercially sold products into my tank and it’s an instant white cloud, but not clumps as I was expecting.

The filter sock is what will remove the bound PO4. Although it works so well in dropping PO4, I went back to GFO and will be trying Rowaphos soon.
 
Phosphate Rx/lanthanum chloride is very effective in “removing” PO4 by binding to it (the white clouds you see) and it IS instantaneous. I’ve poured the commercially sold products into my tank and it’s an instant white cloud, but not clumps as I was expecting.

The filter sock is what will remove the bound PO4. Although it works so well in dropping PO4, I went back to GFO and will be trying Rowaphos soon.

That's why I don't understand what happened. I essentially added the drops to a cup of high phosphate water, mixed it up, and then poured the water through a 10 micron filter sock. The white clouds only showed up the following day in the bottom of the cup, in water that had already been filtered.
 
That's extremely odd. So far as I'm aware, the reaction of lanthanum with phosphate is nearly instantaneous, as you would expect for most ionic solution reactions.

The only thing I can think of is that a good portion of the phosphate in your sample was present as organic phosphate compounds of one sort or another, and the reason for the delayed reaction is that it took some time for these compounds to break down in the water to inorganic phosphate, which then reacted with the lanthanum in solution to form the precipitate that you observed. But this is definitely speculation on my part.

This is definitely a question for Randy - I think he probably knows more about phosphate in organic (living) systems than anyone; and I'd be curious about his opinion, so maybe adding the tag @Randy Holmes-Farley will send him a notification so that he sees this.
 
That's extremely odd. So far as I'm aware, the reaction of lanthanum with phosphate is nearly instantaneous, as you would expect for most ionic solution reactions.

The only thing I can think of is that a good portion of the phosphate in your sample was present as organic phosphate compounds of one sort or another, and the reason for the delayed reaction is that it took some time for these compounds to break down in the water to inorganic phosphate, which then reacted with the lanthanum in solution to form the precipitate that you observed. But this is definitely speculation on my part.

This is definitely a question for Randy - I think he probably knows more about phosphate in organic (living) systems than anyone; and I'd be curious about his opinion, so maybe adding the tag @Randy Holmes-Farley will send him a notification so that he sees this.

Thanks for tagging him. I am very curious to see what he has to say.
 
In a case where po4 is being released from the rock in large amounts over time I would use GFO in a reactor. Lathium to knock it down amd GFO to keep up on the leaching. In time you remove it all from the rock ane be ablemto all but stop using po4 removers.
 
In a case where po4 is being released from the rock in large amounts over time I would use GFO in a reactor. Lathium to knock it down amd GFO to keep up on the leaching. In time you remove it all from the rock ane be ablemto all but stop using po4 removers.

I also have high nitrates, so I guess I need to bring them down together. I’ve started dosing nopox based on other forum members’ recommendations (subject of a different thread). Eventually I do plan to use gfo to maintain po4 in check. Thanks!
 
Following, but, I was always told NOT to use NoPox because it kills too much good bacteria
 

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