Do you have excessive co2 coming out of your GEO? If not, then a second chamber will not do anything so do not sweat it that much. If you do have excessive co2, then you can tune your reactor better. If you have your first chamber tuned well, your tank pH should barely move with the reactor.
ReMag is dolomite. Aragonite and calcite have about the same composition, but are different to melt with the calcite needing a slightly lower pH. I do not think that dolomite or calcite would do anything to use up and extra co2, not that much gets used up anyway without recirculation, so aragonite is probably a good idea in a second chamber.
When using dolomite, most just use a little bit like 20-25% and not 100%. It does not take much. I have only used it when using the man-made media like from AquaMedic, but it was a real pain and I do not use it anymore and prefer natural media.