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On Saturdays I usually check the big 5 (cal, MG, PO , NA, AK) because I do my water changes on Friday night and want to catch any issues ASAP.
What do you mean when you say you test NA? Additionally, Po is the chemical symbol for polonium. If you meant phosphates, that's PO4.
Having said that, If you don't mind testing every day, there's certainly nothing wrong with it. You're right, it doesn't take that much time, and depending on the test kit, the testing costs usually less than a quarter per test.
I would also caution you against assuming that if alkalinity is stable, calcium is as well. This is far from the case, and there are several instances where calcium and carbonate alkalinity are consumed at different rates. Dosing errors will also skew this relationship and cause these elements to become relatively out of sync.



