You're mostly doing fine with the tank....but your nerves might use some relaxing.

I hope I can help on that front...
A) Definitely not worth worrying this much about.....sit back and observe more and try (I know it's hard-especially at this stage) to worry less.
B) 5-10 ppm of NO3 is healthy
and so is normal algae growth. Corals would also use it up if you had any. Normal algae growth is what you control easily with grazers, BTW.
Starving algae, by contrast, is mostly inedible and can have even-worse qualities. (This is somewhat characteristic of all photosynthetic critters.)
C) Check your nutrient balance – N and P. Has your nitrate supply exceeded your phosphate supply? What is your phosphate level?
D) If there is uneaten food for you to get with a turkey baster, you are probably feeding wrong – not feeding too much. (Starving your fish is no better an idea than starving the tank.) Feed only half the amount you are feeding and see if there are still "leftovers". If that works, then just feed that smaller quantity twice as frequently as you normally feed. You can incrementally try to feed more at once to test how much your fish will eat before they start leaving "leftovers" again. I highly recommend an auto-feeder and feeding ring (or equivalent like the Eheim feedingSTATION) to keep your portion size small and feeding frequency more consistent. You should still feed some fresh, unprocessed foods by hand too (as much as possible in fact), so don't over-do it with the feeder, use it to fill in the gaps of time when you can't feed.
E) Doubling your bio-load from
1 fish to 2 fish did not do anything bad to your tank! ....that's one of the best slow progressions in livestocking I can imagine. Adding one fish, then beefing up the CUC and adding a coral, then adding the 2nd fish is the only way to do it better IMO, and that's not a big difference.

I don't think this should be a source of worry for you at all....most folks dump loads of 5-10 fish or corals in at once. (And get colossal algae blooms to match more often than not.)