Even though he is very small, those tangs are poop/pee factories and a 20 qt would be suggested min. for tangs.
Consider some frozen herbivore food and if you can find it some red or purple or brown nori. It's weird how sometimes a tang seems to take to one color or another. Take the nori and wrap it around a rock, secure with a rubber band. Tie a length of fishing line to the rubber band. Easy to lower into the tank and to take it out. Soak the nori in selcon or zoe or zoecon.
Oh and the mark could also be related to the ammonia irritating the skin and then being handled.. Lots of reefers with far more experience than me, often use a 40 breeder tank for tangs, just for the ammonia control you gain with the extra gallons.